INDUSTRIAL WATER TREATMENT ›› 2003, Vol. 23 ›› Issue (4): 57-60. doi: 10.11894/1005-829x.2003.23(4).57

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Researches on the determination of chlorine dioxide, chlorine, chlorite and chlorate in water by potentiometric titriation method

Shi Laishun, Hu Dedong, Xie Yongfang   

  1. School of Chemistry and Chemical Engineering, South Campus, Shandong University, Jinan 250061, China
  • Received:2002-08-28 Online:2003-04-20 Published:2010-10-01

电位滴定法区分测定水中微量ClO2,Cl2,ClO2-及ClO3-的研究

施来顺, 胡德栋, 谢永芳   

  1. 山东大学南校区化学与化工学院, 山东 济南 250061
  • 作者简介:施来顺(1966- ), 1989 年毕业于大连理工大学, 博士, 教授。电话:0531-8392980。

Abstract:

The solid sodium chlorite contents of 20, 10, 5, 2.5, 1 mg/ L and the sodium chlorate (reacted with hydrochloric acid)contents of 20,10, 5,2.5,1 mg/L in water samples are determined respectively by autopoten-tiometric titrator.The recovery rates and detection limits are figured out, respectively.All these show that the potentiometric titrimetry can determine chlorine dioxide, chlorine, chlorite and chlorate at more than 5 mg/L in water quickly and accurately.

Key words: potentiometric titrimetry, chlorine dioxide, concentration

摘要:

利用自动电位滴定仪分别测定了NaClO2固体质量浓度为20mg/L,10mg/L,5mg/L,2.5mg/L,1mg/L和NaClO2(与盐酸反应)质量浓度为20mg/L,10mg/L,5mg/L,2.5mg/L,1mg/L的水样,分别求出其回收率及检出限。试验表明电位滴定法能在5mg/L以上质量浓度快速准确的区分测定ClO2,Cl2,ClO2-和ClO3-。

关键词: 电位滴定法, 二氧化氯, 质量浓度

CLC Number: