Study on treatment of H-acid wastewater by Fenton-like system based on copper slag

doi:10.11894/iwt.2019-0264

Industrial Water Treatment ›› 2020, Vol. 40 ›› Issue (3): 39-42. doi: 10.11894/iwt.2019-0264

• Research and Experiment • Previous Articles Next Articles

Study on treatment of H-acid wastewater by Fenton-like system based on copper slag

Shuai Zhang¹(),Quanyuan Chen^1,^2,³,Jun Lu¹,Mengting Yang⁴

1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, China
2. Shanghai Institute of Pollution Prevention and Ecological Safety, Shanghai 200092, China
3. National Environmental Engineering Engineering Textile Industry Pollution Control Engineering Center, Shanghai 201620, China
4. Shanghai Ship Transportation Science Research Institute, Shanghai 200135, China

Received:2019-12-17 Online:2020-03-20 Published:2020-03-20
Supported by:
国家重点研究发展计划项目(2016YFC0400502);中央高校基本科研业务费(19D111321)

基于铜渣的类Fenton体系处理H酸废水的研究

张帅¹(),陈泉源^1,^2,³,卢钧¹,杨梦婷⁴

1. 东华大学环境科学与工程学院, 上海 201620
2. 上海市污染防治与生态安全研究所, 上海 200092
3. 国家环保工程纺织工业污染治理工程中心, 上海 201620
4. 上海船舶运输科学研究所, 上海 200135

作者简介:张帅(1996-),硕士。电话:18621333052, E-mail:zhangshuai0119@163.com
基金资助:
国家重点研究发展计划项目(2016YFC0400502);中央高校基本科研业务费(19D111321)

Abstract

Abstract:

Fenton-like system composed of copper slag and hydrogen peroxide was used to treat H-acid wastewater. The effects of copper slag input, hydrogen peroxide addition, copper slag particle size and initial pH on the treatment effect were investigated. The results show that under the conditions of n(H₂O₂):m(COD)=55 mmol/g, n(H₂O₂):m(copper slag)=10 mmol/g and initial pH=3, the removal rates of COD and TOC were 70% and 40% after 180 minutes of reaction. Compared with other mineral Fenton-like systems, the treatment effect of H acid wastewater was significantly improved. Copper slag is an effective catalyst for H₂O₂ oxidation of organic pollutants under acidic conditions, and has industrial application possibilities.

Key words: copper slag, Fenton-like, H-acid, catalytic oxidation

摘要：

采用铜渣与双氧水构成类Fenton体系处理H酸废水，考察了铜渣投加量、双氧水投加量、铜渣粒径和初始pH等因素对处理效果的影响。结果表明，在n（H₂O₂）：m（COD）=55 mmol/g、n（H₂O₂）：m（铜渣）=10 mmol/g和初始pH=3的条件下，反应180 min，COD及TOC去除率分别为70%和40%，比其他矿物类Fenton体系对H酸废水的处理效果有明显改善。铜渣在酸性条件下是H₂O₂氧化有机污染物的有效催化剂，有工业应用可能性。

关键词: 铜渣, 类Fenton, H酸, 催化氧化

CLC Number:

X703.1
X791

Shuai Zhang,Quanyuan Chen,Jun Lu,Mengting Yang. Study on treatment of H-acid wastewater by Fenton-like system based on copper slag[J]. Industrial Water Treatment, 2020, 40(3): 39-42.

张帅,陈泉源,卢钧,杨梦婷. 基于铜渣的类Fenton体系处理H酸废水的研究[J]. 工业水处理, 2020, 40(3): 39-42.

/ / Recommend / Download Citations

URL: https://gyscl.magtechjournal.com/EN/10.11894/iwt.2019-0264

https://gyscl.magtechjournal.com/EN/Y2020/V40/I3/39

Figures/Tables 7

References 12

1	周鑫, 唐勇. 2018~2022年中国染料行业发展趋势[J]. 染料与染色, 2018, 55 (1): 11- 23. URL
2	杨志林, 董自斌, 王开春, 等. 络合萃取法预处理H酸废水[J]. 环境科技, 2015, 28 (6): 44- 47. doi: 10.3969/j.issn.1674-4829.2015.06.010
3	宋红, 董振海, 姚慧强, 等. 催化湿式氧化预处理H酸生产废水[J]. 染料与染色, 2017, 54 (6): 52- 54. URL
4	Bianco B , de Michelis I , Vegliò F . Fenton treatment of complex industrial wastewater:Optimization of process conditions by surface response method[J]. Journal of Hazardous Materials, 2011, 186 (2/3): 1733- 1738. URL
5	Kwan W P , Voelker B M . Rates of hydroxyl radical generation and organic compound oxidation in mineral-catalyzed Fenton-like systems[J]. Environmental Science & Technology, 2003, 37 (6): 1150- 1158. URL
6	王爽, 倪文, 王长龙, 等. 铜尾渣深度还原回收铁工艺研究[J]. 金属矿山, 2014, (3): 156- 160. URL
7	Matta R , Hanna K , Chiron S . Fenton-like oxidation of 2, 4, 6-trinitrotoluene using different iron minerals[J]. Science of the Total Environment, 2007, 385 (1/2/3): 242- 251. URL
8	Barreiro J C , Capelato M D , Martin-Neto L , et al. Oxidative decomposition of atrazine by a Fenton-like reaction in a H₂O₂/ferrihydrite system[J]. Water Research, 2007, 41 (1): 55- 62. doi: 10.1016/j.watres.2006.09.016 URL
9	Pouran S R , Aziz A R A , Wan Daud W M A . Review on the main advances in photo-Fenton oxidation system for recalcitrant wastewaters[J]. Journal of Industrial and Engineering Chemistry, 2015, 21, 53- 69. doi: 10.1016/j.jiec.2014.05.005
10	张钰, 顾彦, 杨慧, 等. 赤铁矿光助类Fenton降解有毒有机污染物[J]. 环境科学, 2012, 33 (4): 1247- 1251. URL
11	Quintanilla A , Casas J A , Zazo J A , et al. Wet air oxidation of phenol at mild conditions with a Fe/activated carbon catalyst[J]. Applied Catalysis B:Environmental, 2006, 62 (1/2): 115- 120. doi: 10.1016/j.apcatb.2005.07.001
12	Ali M E M , Gad-Allah T A , Badawy M I . Heterogeneous Fenton process using steel industry wastes for methyl orange degradation[J]. Applied Water Science, 2013, 3 (1): 263- 270. doi: 10.1007/s13201-013-0078-1 URL

元素	质量分数/%	原子占比/%
Fe	36.19	16.71
O	28.95	46.65
Si	11.26	10.34
C	9.55	20.51
Pb	5.14	0.64
Zn	3.86	1.52
Cu	1.98	0.8
Al	1.19	1.14
Na	0.74	0.83
Ca	0.58	0.38
Mg	0.30	0.32
K	0.25	0.16
总量	100	100

元素	质量分数/%	原子占比/%
Fe	36.19	16.71
O	28.95	46.65
Si	11.26	10.34
C	9.55	20.51
Pb	5.14	0.64
Zn	3.86	1.52
Cu	1.98	0.8
Al	1.19	1.14
Na	0.74	0.83
Ca	0.58	0.38
Mg	0.30	0.32
K	0.25	0.16
总量	100	100

[1]	Xiaoyu WU, Shurun YANG, Jiali LIU, Jiamei LIU, Zhihui XIE, Peng ZHOU, Heng ZHANG, Jing ZHANG, Zhaokun XIONG, Chuanshu HE, Bo LAI. Synergistic mechanisms and regulatory principles of metal-pollutant complexation-mediated Fenton-like reactions [J]. Industrial Water Treatment, 2026, 46(2): 19-28.
[2]	Zhiqiang FU, Xinhui TONG, Jianguo JIA, Liang LI, Xizhong AN, Xiaohong YANG. Catalytic oxidation treatment of organic wastewater by ozone/ hydrogen peroxide in a recirculating water reactor [J]. Industrial Water Treatment, 2026, 46(2): 102-110.
[3]	Hang LUO, Shengyin TANG, Yuepeng DENG, Yanyi WANG, Xihui ZHANG. Copper-manganese composite ceramic nanofiber membrane for enhanced Fenton-like degradation of organic pollutants [J]. Industrial Water Treatment, 2025, 45(9): 123-130.
[4]	Hao WU, Cunjie XIA, Menglan WEI, Yimeng WANG, Fei TENG, Xiaoxia OU. Preparation of Cu-doped Bi₂O₂S and its photocatalytic degradation performance of crystal violet [J]. Industrial Water Treatment, 2025, 45(9): 115-122.
[5]	Yunshuang FAN, Xiucui WU, Jiaxin LI, Rui YANG, Jie WANG. Pretreatment of seed coating agent wastewater by coagulation+ electrocatalytic oxidation process [J]. Industrial Water Treatment, 2025, 45(9): 56-63.
[6]	Lei ZOU, Wei XIANG, Yifan WANG, Tao ZHOU, Fengjuan MA, Xiangrong LIU. Efficient degradation of sulfamethoxazole via the activation of persulfate by hydroxylamine/magnetic copper ferrite [J]. Industrial Water Treatment, 2025, 45(8): 43-52.
[7]	Dawei ZHOU, Sijie HU, Yanzhong TAN, Yunhai FENG, Cui LAI, Ming YAN. Mechanism of oxytetracycline removal by Fenton-like system catalyzed by calcium-doped BiOCl [J]. Industrial Water Treatment, 2025, 45(8): 76-82.
[8]	Shuai HOU, Liya FU, Guilin LUO, Jiayu TIAN, Xinhong ZHANG, Hanlu SUN, Junkai WANG, Changyong WU. Research progress and hotspot analysis of catalytic ozonation based on bibliometrics [J]. Industrial Water Treatment, 2025, 45(6): 117-126.
[9]	Hongquan LIU, Shengjie ZHAI, Wenjia LIU, Chongpu WANG, Xinghua KONG, Yanfang LIU, Yu ZHONG. Parameter optimization and effect evaluation of ozone catalytic oxidation technology for urban landscape water [J]. Industrial Water Treatment, 2025, 45(6): 202-210.
[10]	Fu WEN, Yang LI, Chu WANG, Min LI, Jin LI. Optimization of electrocatalytic oxidation treatment of MDEA wastewater by response surface methodology [J]. Industrial Water Treatment, 2025, 45(6): 39-45.
[11]	Guanying WANG, Han GUO, Xinyao LIU, Guangsheng ZHU, Zhiguang SU, Yang LI, Yichen CUI, Junfeng DOU. Technical review of ozone catalytic oxidation for advanced treatment of coking wastewater [J]. Industrial Water Treatment, 2025, 45(5): 29-37.
[12]	Yao WANG, Mingfu CHEN, Jihang WANG, Shuo PENG, Xin ZHOU, Wenhao ZHANG, Lifang JIANG, Yong GUO. Research on ozone degradation of p-nitrophenol catalyzed by ferrous sulfide [J]. Industrial Water Treatment, 2025, 45(4): 92-98.
[13]	Xiangyang TANG, Jun WAN, Jianyang SUN, Yan YAN. Study on treatment of high COD fluorine-containing wastewater [J]. Industrial Water Treatment, 2025, 45(3): 193-197.
[14]	Yixing ZHANG, Yun LI, Huixiang HU. Study on the performance and mechanism of MnFe₂O₄@hydrothermal carbon activated persulfate for tetracycline degradation [J]. Industrial Water Treatment, 2025, 45(12): 88-99.
[15]	Zheng LIU, Long YANG, Zuoxu ZHOU, Lei ZHANG, Xunsheng JI. An advanced treatment project of wastewater from PA66 salt producted by butadiene process [J]. Industrial Water Treatment, 2024, 44(7): 185-189.

Please choose a citation manager

Content to export