High-efficiency catalytic degradation of Rhodamine B in wastewater by MIL-88(Fe) metal organic frameworks

doi:10.11894/iwt.2018-0455

Industrial Water Treatment ›› 2019, Vol. 39 ›› Issue (6): 39-42. doi: 10.11894/iwt.2018-0455

• Research and Experiment • Previous Articles Next Articles

High-efficiency catalytic degradation of Rhodamine B in wastewater by MIL-88(Fe) metal organic frameworks

Juan Li(),Zhaoqin Hu,Guo Zhang,Yarong Duan,Chunmei Luo,Li Yu,Jianxin Xie*()

College of Chemistry Biology and Environment, Yuxi Normal University, Yuxi 653100, China

Received:2019-02-18 Online:2019-06-20 Published:2019-08-07
Contact: Jianxin Xie E-mail:2015208031@yxnu.net;xjx11228@yxnu.net
Supported by:
国家自然科学基金项目(21465024);云南省教育厅科学研究基金重点项目(2014Z147);玉溪师范学院校级大学生创新创业训练计划项目(2016B29)

MIL-88(Fe)金属有机骨架高效催化降解废水中RhB

李娟(),胡照琴,张果,段亚容,罗春梅,禹莉,谢建新*()

玉溪师范学院化学生物与环境学院, 云南玉溪 653100

通讯作者: 谢建新 E-mail:2015208031@yxnu.net;xjx11228@yxnu.net
作者简介:李娟(1996-), E-mail:2015208031@yxnu.net
基金资助:
国家自然科学基金项目(21465024);云南省教育厅科学研究基金重点项目(2014Z147);玉溪师范学院校级大学生创新创业训练计划项目(2016B29)

Abstract

Abstract:

MIL-88(Fe) metal organic frameworks has been used for the high-efficiency catalytic degradation of Rhodamine B(RhB) in dye wastewater by wet method, and characterized by means of FT-IR, XRD, TEM, etc. The effects of MIL-88(Fe) metal organic frameworks on the catalytic degradation of RhB, and its catalytic mechanisms have been investigated. The results show that under optimized conditions, the removing rate of 100 mg/L of RhB by MIL-88(Fe)-H₂O₂ reaction system can reach 99.3%. MIL-88(Fe) metal organic frameworks is expected to become a kind of Fenton-like catalyst for the high-efficiency degradation of organic pollutants in dye wastewater.

Key words: MIL-88(Fe) metal organic frameworks, Rhodamine B, dye wastewater

摘要：

采用MIL-88（Fe）金属有机骨架材料湿法高效催化降解染料废水中罗丹明B。通过FT-IR、XRD和TEM等对MIL-88（Fe）金属有机骨架材料进行了表征，并考察了MIL-88（Fe）金属有机骨架材料催化降解罗丹明B的效果和催化机理。结果表明，在优化条件下，MIL-88（Fe）-H₂O₂反应体系对100 mg/L罗丹明B的去除率可达99.3%。MIL-88（Fe）金属有机骨架材料有望成为一种高效降解染料废水中有机污染物的类Fenton催化剂。

关键词: MIL-88(Fe)金属有机骨架材料, 罗丹明B, 染料废水

CLC Number:

X703

Juan Li,Zhaoqin Hu,Guo Zhang,Yarong Duan,Chunmei Luo,Li Yu,Jianxin Xie. High-efficiency catalytic degradation of Rhodamine B in wastewater by MIL-88(Fe) metal organic frameworks[J]. Industrial Water Treatment, 2019, 39(6): 39-42.

李娟,胡照琴,张果,段亚容,罗春梅,禹莉,谢建新. MIL-88(Fe)金属有机骨架高效催化降解废水中RhB[J]. 工业水处理, 2019, 39(6): 39-42.

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Figures/Tables 7

References 12

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自由基抑制剂	中间体	浓度	抑制率/%
叔丁醇	·OH	0.2 mol/L	74
抗坏血酸	·OH、O₂^·-	0.2 mol/L	60
超氧化歧化酶	O₂^·-	5 mg/L	0.3

自由基抑制剂	中间体	浓度	抑制率/%
叔丁醇	·OH	0.2 mol/L	74
抗坏血酸	·OH、O₂^·-	0.2 mol/L	60
超氧化歧化酶	O₂^·-	5 mg/L	0.3

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