Advances in the research on arsenic-bearing wastewater treatment

doi:10.11894/1005-829x.2012.28(2).10

Abstract

Abstract:

The hazard of arsenic-bearing wastewater and the present situation concerning the technology of its treatment are introduced.The characteristics and limitations of various traditional arsenic removing technologies are analyzed.The application of adsorption method to the treatment of arsenic-bearing wastewater is expounded emphatically in detail.The results show that adsorption method is effective on arsenic removal,as well as on the recycle of arsenic from arsenic-bearing wastewater,and the efficiency depends on the characteristics of the adsorbents.To answer for the requirements of new water quality standard,new materials with low-cost and high-efficiency and strong-stability should be mainly developed in future study.

Key words: arsenic-bearing wastewater, adsorption method, biological method, membrane technology

摘要：

介绍了含砷废水的危害和处理技术发展现状,分析了传统除砷工艺技术的特点及局限性。对吸附法处理含砷废水进行了重点阐述。结果表明,吸附法是同时实现废水除砷和砷资源回收利用的有效技术,而吸附法处理含砷废水的关键在于吸附剂的性能。因此为应对新的生活饮用水水质标准的要求,开发廉价、高效、稳定的新型除砷吸附材料将是重点关注的研究方向。

关键词: 含砷废水, 吸附法, 生物法, 膜技术

CLC Number:

X703.1

Gao Xiaojuan, Wang Fan, Wang Qinian. Advances in the research on arsenic-bearing wastewater treatment[J]. INDUSTRIAL WATER TREATMENT, 2012, 32(2): 10-15.

高小娟, 王璠, 汪启年. 含砷废水处理研究进展[J]. 工业水处理, 2012, 32(2): 10-15.

/ / Recommend / Download Citations

URL: https://gyscl.magtechjournal.com/EN/10.11894/1005-829x.2012.28(2).10

https://gyscl.magtechjournal.com/EN/Y2012/V32/I2/10

References

[1] 牛秋雅.砷污染治理及砷资源回收利用的清洁生产新技术研究[D].湖南:湖南大学,2001.
[2] 龙大祥.铜冶炼含砷污水处理[J].工业用水与废水,2000,31(41):30-32.
[3] 杨洁,顾海红,赵浩,等.含砷废水处理技术研究进展[J].工业水处理,2003,23(6):14-18.
[4] 方兆珩,石伟,韩宝玲,等.高砷溶液中和脱砷过程[J].化工冶金,2000,21(4):359-362.
[5] 张永忠,郭雄.砷的地球化学与健康[J].国外医学(医学地理分册),2007,28(2):49-51.
[6] Jeffer A L,Robert F S,Christopher T D.Environmental Toxicants[M].New York:National Academies Press,1993:20-50.
[7] 张庆建,张炜铭,潘丙才,等.载铁复合环境材料的制备及对水体中砷的深度净化[J].离子交换与吸附,2009,25(3):282-288.
[8] 陈敬军.Fe(Ⅲ)负载型螯合树脂吸附砷(Ⅴ)的研究[D].南昌:南昌大学,2005.
[9] 庄明龙,柴立元,闵小波,等.含砷废水处理研究进展[J].工业水处理,2004,24(7):13-17.
[10] Kim M J,Nriagu J.Oxidation of arsenite in groundwater using ozone and oxygen[J].The Science of Total Environment,2000,247 (1):71-79.
[11] Pettine M,Campanella L,Millero F J.Arsenite oxidation by H₂O₂ in aqueous solutions[J].Geochimica et Cosmochimica Acta,1999,63(18):2727-2735.
[12] 陈红,方士.用MnO₂氧化废水中As(Ⅲ)为As(Ⅴ)的特性[J].高校化学工程学报,2000,14(1):48-52.
[13] 施建兵,林集先,邱凌峰.高铁酸盐在微污染源水除砷中的应用效果及其影响因素研究[J].能源与环境,2008(1):80-82.
[14] 闵世俊,曾英,韩璐,等.含砷工业废水处理现状与进展[J].广东微量元素科学,2008,15(8):1-7.
[15] 许根福.处理高砷浓度工业废水的化学沉淀法[J].湿法冶金,2009,28(1):12-17.
[16] 杨力.砷污染及含砷废水治理[J].有色金属加工,1999,(4):27-29.
[17] 菀宝玲,李坤林,邓临莉,等.多功能高铁酸盐去除饮用水中砷的研究[J].环境科学,2006,27(2):281-284.
[18] 谢晓梅,廖敏,石伟勇,等.稀土的应用研究——铈在含砷废水处理中的应用[J].广东微量元素科学,1999,6(6):7-11.
[19] 胡天觉,曾光明,陈维平,等.选择性高分子离子交换树脂处理含砷废水[J].湖南大学学报,1998,25(6):75-80.
[20] Vagliasindi F G A,Candidate D,Benjamin M.Arsenic removal in fresh and NOM-preloaded ion exchange packed bed adsorption reactors[J].Water Science and Technology,1998,38(6):337-343.
[21] 刘振中,邓慧萍,韩瑛,等.离子交换纤维除As(Ⅴ)性能研究[J].工业水处理,2009,29(8):62-66.
[22] 夏圣骥,高乃云,张巧丽,等.纳滤膜去除水中砷的研究[J].中国矿业大学学报,2007,36(4):565-568.
[23] Brandhuber P,Amy G.Arsenic removal by a charged ultrafiltration membrane-influences of membrane operating conditions and water quality on arsenic rejection[J].Desalination,2001,140 (1):1-14.
[24] 杨宏,尹瑞,张杰.生物除锰滤池对砷(Ⅲ)的去除效果研究[J].中国给水排水,2006,22(7):85-88.
[25] 廖敏,王锐.菌藻共生体去除废水中砷初探[J].环境污染与防治,1997,19(2):11-12.
[26] 张萃,李亚峰,田西满.活性炭吸附处理含砷废水的研究[J].工业安全与环保,2009,35(12):6-7.
[27] 张巧丽,高乃云,乐林生,等.氧化铁/活性炭复合吸附材料去除水中砷的研究[J].同济大学学报:自然科学版,2006,34(12):1647-1650.
[28] 孙迎涛,姜雪松,刘建国.用活化粉煤灰处理含砷废水的试验研究[J].甘肃环境研究与监测,2003,16(4):344-345.
[29] 陈云嫩,柴立元,舒余德.骨炭去除水中砷(Ⅴ)的试验研究[J].中南大学学报:自然科学版,2008,39(2):279-283.
[30] 那平,张帆,杨曙锋,等.水热法制备钛柱撑蒙脱石及对水体中砷酸根的吸附[J].天津大学学报,2007,40(3):275-279.
[31] 刘建,闫英桃,王慧.高岭土的改性及其从含砷水中除砷性能研究[J].应用化工,2009,38(8):1100-1104.
[32] Wasay S A,Haron M D J,Tokunaga S.Adsorption of fluoride,phosphate,and arsenate ions on lanthanum-impregnated silica gel[J].Water Environment Research,1996,68(3):295-300.
[33] 张昱,杨敏,王桂燕,等.利用稀土基无机合成材料去除饮用水中砷的研究[J].环境化学,2001,20(1):70-75.
[34] 张昱,豆小敏,杨敏,等.砷在金属氧化物/水界面上的吸附机制Ⅰ.金属表面羟基的表征和作用[J].环境科学学报,2006,26(10):1586-1591.
[35] 肖亚兵,钱沙华,黄淦泉,等.纳米二氧化钛对砷(Ⅲ)和砷(Ⅴ)吸附性能的研究[J].分析科学学报,2003,19(2):172-174.
[36] 喻德忠,邹菁,艾军.纳米二氧化锆对砷(Ⅲ)和砷(Ⅴ)的吸附性质研究[J].武汉化工学院学报,2004,26(3):1-3.
[37] 彭长宏,程晓苏,曹金艳,等.离子液体负载型碳纳米管吸附除砷研究[J].中南大学学报:自然科学版,2010,41(2):416-421.
[38] 梁慧锋,马子川,张杰,等.新生态MnO₂对水中As(Ⅴ)的吸附作用研究[J].安全与环境学报,2005,5(1):50-53.
[39] 梁慧锋,王秀玲,马子川,等.MnO₂负载树脂的制备及对As(Ⅴ)的去除效果[J].环境污染治理技术与设备,2006,7(10):73-76.
[40] 饶品华,肖稳发,徐菁利,等.天然有机物对零价铁去除水体中砷的影响研究[J].环境污染与防治,2009,31(6):43-49.
[41] 张岚,岳银玲,李淑敏.铁屑对饮用水中砷的去除效果评价[J].卫生研究,2008,37(3):347-348.
[42] 叶瑛,季珊珊,邬黛黛,等.针铁矿及其前体吸附亚砷酸根离子的反应及预处理方法的影响[J].岩石矿物学杂志,2005,24(6):551-555.
[43] Driehaus W,Jekel M,Hildebrandt U.Granular ferric hydroxide-a new adsorbent for the removal of arsenic from natural water[J].Journal of Water Supply,1998,47 (1):30-35.
[44] Gu Zhimang,Fang Jun,Deng Baolin.Preparation and evaluation of GAC-based iron-containing adsorbents for arsenic removal[J].Environ.Sci.Technol.,2005,39(10):3833-3843.
[45] Min J H,Hering J G.Arsenate sorption by Fe (Ⅲ)-doped alginate gels[J].Water Research,1998,32(5):1544-1552.
[46] 赵雅萍,王军锋,陈甫华.载铁(Ⅲ)-配位体交换棉纤维素吸附剂对饮用水中砷(Ⅴ)和氟联合去除的研究[J].高等学校化学学报,2003,24 (4):643-647.
[47] Ghimire K N,Inoue K,Yamaguchi H,et al.Adsorptive separation of arsenate and arsenite anions from aqueous medium by using orange waste[J].Water Research,2003,37(20):4945-4953.
[48] Jang M,Min S H,Kim T H,et al.Removal of arsenite and arsenate using hydrous ferric oxide incorporated into naturally occurring porous diatomite[J].Environ.Sci.Technol.,2006,40 (5):1636-1643.
[49] 陈新庆,潘丙才,潘丙军,等.新型树脂基水合氧化铁对水体中微量砷的吸附性能研究[J].离子交换与吸附,2007,23(1):16-23.
[50] 潘丙才,张庆建,陈新庆,等.基于Donnan膜效应的树脂基水合氧化铁的制备及对砷的吸附性能研究[J].中国科学,2007,37(5):426-431. and pesticides using wheat straw as substrates[J].Process Biochemistry,2005,40(2):935-943.

Please choose a citation manager

Content to export