INDUSTRIAL WATER TREATMENT ›› 2006, Vol. 26 ›› Issue (7): 53-56. doi: 10.11894/1005-829x.2006.26(7).53

Previous Articles     Next Articles

Study on fluoride removal of doxycycline was tewater

Zhang Ling1, Li Deliang1, Li Guimin1, Li Weiqing2   

  1. 1. Chemistry and Chemical Engineering College of Henan University, Kaifeng 475001, China;
    2. Henan Institute of Environmental Protection, Zhengzhou 450004, China
  • Received:2006-02-20 Online:2006-07-20 Published:2010-10-01

强力霉素废水中氟的处理研究

张凌1, 李德亮1, 李桂敏1, 李尉卿2   

  1. 1. 河南大学化学化工学院, 河南开封 475001;
    2. 河南省环保研究所, 河南开封 475004
  • 作者简介:张凌(1965- ),1989 年毕业于河南大学化学系,硕士研究生,高级工程师。E-mail:lideliang@henu.edu.cn。
  • 基金资助:

    河南省国际科技合作资助课题(200546640002)

Abstract:

Based on characteristics of fluoride-containing wastewater from doxycycline, it can be treated by lime - fly ash process with two-stage purification. The primary factors effecting the disposal efficiency are experimentally studied. The results of tests show that the optimal conditions are controlling m(Ca):m(F)= 2 and reaction time 40 min of the first stage; controlling grain size of fly ash<200 mesh, ratio of fly ash and water 1:10, adsorption time 200 min, pH 4-8 of the second stage. Fluoride of the treated wastewater is less than 10mg/L, come up to the First Class National Discharge Standard (GB 8978-1996). Meanwhile this method is simple to operate and has lower operational cost. It is suggested that making brick with used mortar should be a good disposal method without causing secondary pollution to the environment. Furthermore, this wastewater can be treated by waste.

Key words: doxycycline wastewater, fluoride removal, chemical deposition method, fly ash adsorption

摘要:

根据强力霉素含氟废水的特点,采用石灰-粉煤灰两段净化工艺处理其中的氟,并对影响处理效果的主要因素进行了试验研究。结果表明,一段处理最佳条件:m(Ca):m(F)=2、反应时间40 min;二段处理最佳条件:粉煤灰粒径小于200目,灰水比为1:10,振荡吸附时间为200 min,pH4~8;处理后的废水中氟质量浓度<10mg/L,达到了GB 8978-1996《污水综合排放标准》中的一级标准。该方法工艺简单、操作方便、成本低廉。处理废水后的含氟灰渣烧制成砖块,不会对环境造成二次污染,并达到了以废治废的目的。

关键词: 强力霉素废水, 除氟, 化学沉淀法, 粉煤灰吸附法

CLC Number: